Search results for "Microstructural changes"

showing 2 items of 2 documents

Aroma behaviour during steam cooking within a potato starch-based model matrix.

2012

To help understand the organoleptic qualities of steam cooked foods, the kinetics of aroma release during cooking in a potato starch based model matrix was studied. Behaviour of components having a major impact in potato flavour were studied using solid phase micro extraction-gas chromatography (SPME-GC). Evolution of microstructure of potato starch model-matrix during steam cooking process was analyzed using environmental scanning electron microscopy (ESEM). Both aroma compounds that are naturally present in starch matrix and those that were added were analyzed. Both the aroma compounds naturally presented and those added had different behaviour depending on their physico-chemical properti…

Polymers and PlasticsbiologyChemistryStarchOrganic ChemistryFlavourOrganolepticfood and beveragesStarchbiology.organism_classificationMatrix (chemical analysis)chemistry.chemical_compoundStarch gelatinizationSteamOdorantsMaterials Chemistrypotato starch; steam cooking; aroma compounds; aromatization; mMicrostructural changesMicroscopy Electron ScanningOrganic chemistryFood scienceCookingEnvironmental scanning electron microscopePotato starchAromaSolanum tuberosumCarbohydrate polymers
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The role of crystalline, mobile amorphous and rigid amorphous fractions in the performance of recycled poly (ethylene terephthalate) (PET)

2012

[EN] The action of thermo-mechanical degradation induced by mechanical recycling of poly(ethylene terephthalate) was simulated by successive injection moulding cycles. Degradation reactions provoked chain scissions and a reduction in molar mass mainly driven by the reduction of diethyleneglycol to ethylene glycol units in the flexible domain of the PET backbone, and the formation of -OH terminated species with shorter chain length. The consequent microstructural changes were quantified taking into account a three-fraction model involving crystalline, mobile amorphous (MAF) and rigid amorphous fractions (RAF). A remarkable increase of RAF, to a detriment of MAF was observed, while the percen…

EthyleneSolucions polimèriquesPolymers and PlasticsInjection mouldingDifferential scanning calorimetry (DSC)Crystalline fractionsMechanical propertiesThermo-mechanical degradationchemistry.chemical_compoundDegradationAmorphous materialsPolymer blendsMaterials ChemistryMechanical recyclingRecyclingComposite materialDiethyleneglycolPoly(ethylene terephthalate) (PET)Injection moldingMolar massMechanical featureRecycled poly(ethylene terephthalate)Microstructural changesCondensed Matter PhysicsChain scissionRigid-amorphous fractionMechanics of MaterialsMAQUINAS Y MOTORES TERMICOSPolymer blendMaterials scienceMechanical performanceViscoelasticityEthyleneDifferential scanning calorimetrySegmental dynamicsInfrared analysis (FT-IR)Degradation reactionDifferential scanning calorimetryInjection mouldingPolyethylene terephthalatesEthylene glycolTermoplàsticsCrystalline materialsShorter chainsAmorphous solidchemistryGlass-rubber relaxationProcessing cyclesEthylene glycol
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